Add the second disk by entended the rootvg (hdisk1 in this example)
# extendvg rootvg hdisk1 0516-1254 extendvg: Changing the PVID in the ODM.
Mirror the original disk with the new disk
# mirrorvg rootvg hdisk0 hdisk1 0516-1124 mirrorvg: Quorum requirement turned off, reboot system for this to take effect for rootvg. 0516-1126 mirrorvg: rootvg successfully mirrored, user should perform bosboot of system to initialize boot records. Then, user must modify bootlist to include: hdisk0 hdisk1.